Use collencoding = -1 to represent such a collation in pg_collation.
We need this to make the "default" entry work sanely, and a later
patch will fix the C/POSIX entries to be represented this way instead
of duplicating them across all encodings.  All lookup operations now
search first for an entry that's database-encoding-specific, and then
for the same name with collencoding = -1.

Also some incidental code cleanup in collationcmds.c and pg_collation.c.