Index columns are referenced by ordinal number rather than name, e.g.
CREATE INDEX coord_idx ON measured (x, y, (z + t));
ALTER INDEX coord_idx ALTER COLUMN 3 SET STATISTICS 1000;

Incompatibility note for release notes:
\d+ for indexes now also displays Stats Target

Authors: Alexander Korotkov, with contribution by Adrien NAYRAT
Review: Adrien NAYRAT, Simon Riggs
Wordsmith: Simon Riggs